Orbital control on cyclical organic matter accumulation in Early Silurian Longmaxi Formation shales

High resolution(939 samples)total organic carbon content(TOC)analyses were conducted on the Shuanghe Section of^152.6 m in the Changning area,Sichuan Basin.The sampling section was divided into two units considering the distinct-different deposit environment and sediments accumulation rate.The lower part(Unit 1)and the peer part(Unit 2)with high resolution sample spacing(0.08–0.4 m)enables the identification of the precession cycle in two sedimentary sequences with distinct different sedimentary accumulation rate.MTM Power spectral analyses on untuned TOC series reveals significant peaks exceeding above the 95%confidence level and shows that both Unit 1 and Unit 2 have recorded Milankovitch cycles of 405 kyr long eccentricity,short eccentricity,obliquity and precession.The floating astronomical time scale(ATS)was constructed on the Shuanghe Section in the Early Silurian(~439.673–444.681 Ma),and which was calibrated by 405 kyr long eccentricity cycles.The total duration of the Wufeng and Longmaxi shales is 5.01 Myr.The floating ATS used for estimating the duration of the graptolite zones and each stage in the study interval.Finally,we postulated two models that could verify the linkage between orbital cycle and organic accumulation.To make sure whether productivity or preservation is the main factor that under long eccentricity control,the phase correlation between the obtained filtered signal and the theoretical orbital solution should be made clear in the further research.     

古太平洋板块俯冲-增生时限：饶河增生杂岩的地球化学和年代学制约

饶河杂岩作为那丹哈达增生杂岩的主体,是古太平洋板块西向俯冲的直接证据。饶河增生杂岩组成与增生过程的研究对限定古太平洋板块向欧亚大陆的俯冲与增生过程具有重要的指示意义。本文在野外地质调查和饶河大岱地区大比例尺填图基础上,明确了饶河杂岩主要由枕状玄武岩、辉长岩以及大洋板块沉积地层(OPS)组成,这些岩石均呈构造透镜体状分布在海沟沉积物中,并被中生代花岗质岩脉所穿切,因此为限定饶河增生杂岩的组成、增生和就位时代提供了关键制约。地球化学数据表明玄武岩具有洋岛玄武岩(OIB)的地球化学属性。LA-ICPMS锆石测试结果表明该地区玄武岩和辉长岩的形成时代分别为166±2Ma和214±5Ma,限定了饶河杂岩中镁铁质-超镁铁质岩石的形成时代为晚三叠世至中侏罗世。结合该区粉砂质泥岩和砂岩的沉积时代下限分别为167±3Ma和133±4Ma,表明饶河杂岩的增生时代为167～133Ma,此外样品的碎屑年龄信息表明基质的物源为邻近的佳木斯地块和中亚造山带东段,其中前寒武的碎屑年龄在中国东北的多个陆块均有出现,可能源于早前存在的前寒武纪基底。本文测得侵入饶河杂岩的2个二长花岗岩形成年龄分别为126±1Ma和105±2Ma,表明饶河杂岩中的花岗岩脉主要形成于两个阶段,其中较老的花岗岩侵入体进一步限定了饶河杂岩的最终就位时代为133Ma至126Ma,表明古太平洋板块在中侏罗世至早白垩世存在西向俯冲-增生作用,为古太平洋板块的构造演化提供了重要的制约。     

Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.     

探秘“能源新星”——干热岩

干热岩是近些年逐渐发展起来的清洁能源，指埋藏于地球表面3000 m以深，不含或含少量水或蒸汽等流体，温度在180 ℃以上且渗透率极低的岩体。对干热岩的应用主要是建立增强型地热系统进行发电。目前对干热岩的研究尚处于起步阶段,干热岩的热源、热储、形成机理、埋藏机制等都未形成完整的理论体系，干热岩的开发过程也面临诸如储层改造、高温钻探以及随钻监测等一系列的技术“瓶颈”。干热岩资源储量大，开发利用过程低碳环保、节能高效，是国际社会公认的优质清洁能源，但是干热岩研究程度低，开发难度大，需要不断的知识积累和技术积累。本文从科普的角度列举了干热岩的相关研究现状及存在的问题，以期能让更多的人对这一“能源新星”加深了解。     

硼的地球化学性质及其在俯冲带的循环与成矿初探

硼是广泛应用于化工、农业、材料科学及核工业领域的重要元素。硼与氢的核聚变反应是未来具备运用潜力的清洁能源。硼作为典型的亲石元素,是高度不相容元素。硼元素容易富集于蚀变洋壳及蛇纹石化地幔橄榄岩中。而在板块俯冲过程中,由于硼具有强的流体活动性,会优先赋存于流体中。因此,当蛇纹石化的大洋岩石圈及覆于其上的沉积物在俯冲过程中发生脱水,这使得弧前地幔楔发生大规模的蛇纹石化。此时大量硼元素很可能随俯冲流体释放并封存于弧前地幔楔中。目前已发现的超大型硼矿床主要位于聚合型板块边缘,尤其土耳其拥有世界上最大的硼酸盐储量。我们推测这些矿床的形成基础条件之一可能与弧前高度蛇纹石化的地幔楔有关。尤其是在洋 陆俯冲环境,弧前蛇纹岩或蛇绿混杂岩首先通过俯冲侵蚀再循环到火山弧岩浆中,使得岩浆更富集硼。随后弧火山喷发大量富硼的火山岩、岩浆热液及水气。在岩浆冷却过程中,硼元素析出、沉淀于火山表面,并伴随风化、侵蚀过程汇聚至碰撞造山带的封闭湖盆之中。此外,干冷的气候条件下也进一步促进了硼的成矿。我国具有形成大型、超大型硼矿的地质条件,应加大研究及探勘力度,并适当购买硼作为战略储备。     

东海盆地中、新生代盆架结构与构造演化

基于地貌、钻井、岩石测年和地震等资料,分析盆地地层分布、盆架结构、构造单元划分和裂陷迁移规律,结果表明东海盆地由台北坳陷、舟山隆起、浙东坳陷、钓鱼岛隆褶带和冲绳坳陷构成,是以新生代沉积为主、中生代沉积为辅的大型中、新生代叠合含油气盆地;古元古代变质岩系构成了盆地的基底。该盆地不仅是印度-太平洋前后相继的动力体系作用下形成的西太平洋沟-弧-盆构造体系域一部分,而且也是古亚洲洋动力体系作用下形成的古亚洲洋构造域和特提斯洋动力体系作用下形成的特提斯洋构造域一部分,晚侏罗世至早白垩世经历了构造体制转换,盆地格局发生重大变革,早白垩世以前主要受古亚洲-特提斯洋构造体制影响的强烈挤压造山和地壳增厚作用演变为早白垩世以来主要受太平洋构造体制控制的陆缘伸展裂陷和岩石圈减薄作用,经历侏罗纪古亚洲-特提斯构造体制大陆边缘拗陷和白垩纪以来太平洋构造体制弧后裂陷两大演化阶段。白垩纪以来太平洋构造体制的弧后裂陷演化阶段可细分为早白垩世至始新世裂陷期、渐新世至晚中新世拗陷期和中新世末至全新世裂陷期。     

胶东纱岭金矿床构造叠加晕特征及深部找矿预测

纱岭金矿床位于焦家断裂中南段,属于典型的焦家式金矿床,探获金资源量约389.2t,目前是国内平均勘查深度最大的金矿床。为进一步探讨纱岭金矿床深部成矿潜力,该文在野外地质工作的基础上,选取钻孔岩心样品,采用构造叠加晕研究方法,重点研究Ⅰ-2号主矿体地球化学特征、原生晕分带特征,建立构造叠加晕模型并进行深部找矿预测。研究结果表明:矿床的前缘晕指示元素为As-Sb-Hg,近矿晕指示元素为Au-Ag-Cu-Pb-Zn,尾晕指示元素为Bi-Mo-W-Sn;Ⅰ-2号主矿体构造叠加晕出现"反分带"现象,表明纱岭金矿床具有多期成矿成晕特征;在矿体尾部存在前缘晕与尾晕共存叠加现象,指示深部有良好的找矿前景,预测矿体侧伏方向深部(-1600m之下)有盲矿存在,预测靶位标高为-1600m～-2000m。     

水平分支注浆孔卡埋钻事故处理实践

近年来煤矿奥灰治水注浆定向钻进技术发展迅速，多分支超深水平注浆孔数量激增。在水平注浆孔施工过程中，普遍存在地层漏失量大，泥浆突然失返，小径钻孔裸孔段长，水平段孔眼轨迹复杂，控制难度大，靶点技术误差要求严，定向仪器、工具等价格昂贵，施工风险相对较高，极易发生埋钻卡钻事故。一旦发生卡钻事故，就会面临着处理周期长、处理难度大等问题，传统的卡埋钻处理方法在水平注浆孔中应用效果不明显。通过采用空压机输送压缩空气，破坏水平孔着床的沉砂结构，将着床的沉砂吹出孔外或吹入地层裂隙，成功地实现了解卡。总结了水平注浆孔施工中卡埋钻事故的预防措施。     

特定场地下土工构筑物的几何可靠性分析

针对特定场地下土工构筑物的正常使用极限状态，采用近年发展的几何可靠性方法计算了多种构筑物的可靠度指标。考虑同一场地下的钻孔灌注桩、抗浮锚杆和CFG桩单桩加载变形测试曲线的离散性，各曲线回归参数呈现差异并可作为随机变量，进而探讨了各曲线回归参数间的相关性及联合分布特性。基于这些回归参数的联合发散概率密度等值线，即随机变量刚好达到极限承载能力状态，该几何可靠性算法可在随机变量的原始空间求得土工构筑物的可靠度指标。通过比对该几何可靠度指标与常规的一次可靠性算法成果，验证了该几何可靠性计算技术的可行性。计算表明，几何可靠性评价模型实施简便，易于被工程技术人员接受。     

基于引文分析法的“点-轴系统”理论研究述评

论文采用引文分析法,对陆大道院士所著《关于“点-轴”空间结构系统的形成机理分析》一文的349篇引文进行分析,从引文数量、引文作者、发文期刊、研究案例地、学科领域、研究主题、引用动机7个方面,探究“点-轴系统”理论的研究现状。结果表明：自2002年以来,“点-轴系统”理论的引文数量整体呈上升趋势,研究主题聚焦于区域经济和旅游发展;研究案例地以省级和市级中观尺度为主,多为单一型研究区,主要集中在西北丝绸之路经济带、东北辽宁经济圈、西南藏滇川渝、东部长三角四大热点区域;引文质量普遍较高,并且具有多学科交叉应用的特点,但批判性思考和创造性提升相对较少。基于此,论文从拓展研究和实践应用2个角度对“点-轴系统”理论未来发展进行了展望,以期为相关研究提供参考。